SERS-эффект на поверхности наностержней ZnO, покрытых CsPbBr3
DOI:
https://doi.org/10.33910/2687-153X-2026-7-1-3-15Ключевые слова:
наностержни ZnO, наночастицы CsPbBr3, SERS-эффект, комбинационное рассеяние света, гетероструктуры, перенос энергии, низкочастотные фононыАннотация
Гетероструктуры на основе наностержней ZnO и наночастиц CsPbBr3 были исследованы с целью оценки их потенциала в качестве полупроводниковых SERS-субстратов. Было выявлено, что морфология ZnO определяет эффективность межфазного переноса энергии, увеличивая фотолюминесценцию при длине возбуждения 390 нм и вызывая снижение ширины запрещенной зоны в композитах. Анализ спектров комбинационного рассеяния выявил значительное усиление интенсивности и появление низкочастотных мод CsPbBr3, выделенных с помощью гауссовой деконволюции, что подтверждает SERS-подобное поведение гибридных структур. Полученные результаты демонстрируют перспективность ZnO/CsPbBr3-гетероструктур для сенсорики и оптоэлектронных приложений.
Библиографические ссылки
Ahmed, M. A., Abou-Gamra, Z. M., Alshakhanbeh, M. A. Medien, H. (2019) Control synthesis of metallic gold nanoparticles homogeneously distributed on hexagonal ZnO nanoparticles for photocatalytic degradation of methylene blue dye. Environmental Nanotechnology, Monitoring & Management, 12, article 100217. https://doi.org/10.1016/j.enmm.2019.100217 (In English)
Alagurasu, A., Behera, S., Yang, J.-M. et al. (2025) Large-area nanogap platforms for surface-enhanced Raman spectroscopy toward sensing applications: Comparison between Ag and Au. Biosensors, 15 (6), article 369. https://doi.org/10.3390/bios15060369 (In English)
Averochkin, E. P., Steparuk, A. S., Teksina, E. V. et al. (2024) Photoactive Layers based on ZnO Nanorods obtained by hydrothermal synthesis for dye-sensitized solar cells. Russian Journal of Inorganic Chemistry, 69 (6), 925–932. https://doi.org/10.1134/S0036023624600734 (In English)
Bakry, M., Ismail, W., Abdelfatah, M., El-Shaer, A. (2024) Low-cost fabrication methods of ZnO nanorods and their physical and photoelectrochemical properties for optoelectronic applications. Scientific Reports, 14, article 23788. https://doi.org/10.1038/s41598-024-73352-5 (In English)
Benadia, A. G., Pan, L., Bayikadi, K. S. et al. (2025) Progress in solution growth of cuboid CsPbBr3 single crystals with low defect densities and high-sensitivity X-ray detection. Crystal Growth & Design, 25 (21), 9288–9299. https://doi.org/10.1021/acs.cgd.5c01107 (In English)
Chiu, Y.-H., Chang, K.-D., Hsu, Y.-J. (2018) Plasmon-mediated charge dynamics and photoactivity enhancement for Au-decorated ZnO nanocrystals. Journal of Materials Chemistry A, 6 (10), 4286–4296. https://doi.org/10.1039/C7TA08543E (In English)
Coulter, J. B., Birnie, D. P. III (2018) Degradation mechanism in methylammonium lead iodide perovskite by water: Formation of hydrated HI and PbI2. Physica Status Solidi B, 255 (3), article 1700393. https://doi.org/10.1002/pssb.201700393 (In English)
Deng, S., Fan, H. M., Zhang, X. et al. (2009) An effective surface-enhanced Raman scattering template based on a Ag nanocluster–ZnO nanowire array. Nanotechnology, 20, article 175705. https://doi.org/10.1088/0957-4484/20/17/175705 (In English)
Djurisic, A. B., Chen, X., Leung, Y. H., Ng, A. M. C. (2012) ZnO nanostructures: Growth, properties and applications. Journal of Materials Chemistry, 22, 6526–6535. https://doi.org/10.1039/C2JM15548F (In English)
Dubkov, S. V., Novikov, D. V., Bandarenka, H. V. et al. (2024) Express formation and characterization of SERS-active substrate from a non-degradable Ag-Nb-N-O film. Applied Surface Science, 645, article 158682. https://doi.org/10.1016/j.apsusc.2023.158682 (In English)
Gushchina, V. A., Son, A. G., Egorova, A. A. et al. (2024) Synthesis, structures, and optical properties of semiconductor perovskite nanoparticles CsBX3 (B = Pb, Mn; X = Br, Cl). Russian Journal of Inorganic Chemistry, 69, 940–948. https://doi.org/10.1134/S0036023624600928 (In English)
Han, X. X., Ji, W., Zhao, B. Ozaki, Y. (2017) Semiconductor-enhanced Raman scattering: active nanomaterials and applications. Nanoscale, 9, 4847–4861. https://doi.org/10.1039/C6NR08693D (In English)
Hasabeldaim, E. H. H., Ntwaeaborwa, O. M., Kroon, R. E. et al. (2019) Enhanced green luminescence from ZnO nanorods. Journal of Vacuum Science & Technology B, 37 (1), article 011201. https://doi.org/10.1116/1.5052543 (In English)
Iaru, C. M., Brodu, A., van Hoof, N. J. J. et al. (2021) Fröhlich interaction dominated by a single phonon mode in CsPbBr3. Nature Communications, 12 (1), article 5844. https://doi.org/10.1038/s41467-021-26192-0 (In English)
Jin, L. She, G., Li, J. et al. (2016) A facile fabrication of Ag-Au-Ag nanostructures with nanogaps for intensified surface-enhanced Raman scattering. Applied Surface Science, 389, 67–72. http://dx.doi.org/10.1016/j.apsusc.2016.07.066 (In English)
Kim, K. H., Utashiro, K., Abe, Y., Kawamura, M. (2014) Structural Properties of Zinc Oxide Nanorods Grown on Al-Doped Zinc Oxide Seed Layer and Their Applications in Dye-Sensitized Solar Cells. Materials, 7 (4), 2522–2533. https://doi.org/10.3390/ma7042522 (In English)
Kim, S., Jin, J., Kim, Y.-J. et al. (2008) High-harmonic generation by resonant plasmon field enhancement. Nature, 453, 757–760. https://doi.org/10.1038/nature07012 (In English)
Korepanov, V. I. Chan, Si-Y., Hsu, H.-C., Hamaguchi, H. (2019) Phonon confinement and size effect in Raman spectra of ZnO nanoparticles. Heliyon, 5 (2), article e01222. https://doi.org/10.1016/j.heliyon.2019.e01222 (In English)
Kumar, R., Umar, A., Kumar, G. et al. (2017) Zinc oxide nanostructure-based dye-sensitized solar cells. Journal of Materials Science, 52, 4743–4795. https://doi.org/10.1007/s10853-016-0668-z (In English)
Kumar, V., Gupta, R., Bansal, A. (2021) Hydrothermal growth of ZnO nanorods for use in dye-sensitized solar cells. ACS Applied Nano Materials, 4, 6212–6222. https://doi.org/10.1021/acsanm.1c01012 (In English)
Lee, S., Cho, S., Jeong, S.-H. et al. (2025) Inverted CsPbI3 perovskite solar cells with all solution processed layers fabricated in high humidity. Communications Materials, 6, article 72. https://doi.org/10.1038/s43246-025-00796-1 (In English)
Leelavathi, A., Madrasa, G., Ravishankar, N. (2013) Size-dependent optical properties of ZnO nanocrystals. Physical Chemistry Chemical Physics, 15, 10795–10803. https://doi.org/10.1039/C3CP51058A (In English)
Li, S., Yuan, M., Zhuang, W. et al. (2021) Optically-controlled quantum size effect in a hybrid nanocavity composed of a perovskite nanoparticle and a thin gold film. Laser & Photonics Reviews, 15 (12), article 2000480. https://doi.org/10.1002/lpor.202000480 (In English)
Majee, B. P., Bhawna, Mishra, A. K. (2020) Bi-functional ZnO nanoparticles as a reusable SERS substrate for nano-molar detection of organic pollutants. Materials Research Express, 6, article 1250j1. https://doi.org/10.1088/2053-1591/ab6f31 (In English)
Majumdar, D. (2024) 2D material-based surface-enhanced Raman spectroscopy platforms (either alone or in nanocomposite form)-from a chemical enhancement perspective. ACS Omega, 9 (38), 40242–40258. https://doi.org/10.1021/acsomega.4c06398 (In English)
Miao, J., Liu, Y., Xiao, Y. et al. (2025) Water-stable perovskite/metallic nanocomposites-based SERS aptasensor for detection of neuron-specific enolase. Biosensors and Bioelectronics, 280, article 117462. https://doi.org/10.1016/j.bios.2025.117462 (In English)
Novikov, D. V., Malakhov, N. S, Tarasov, A. M. et al. (2021) Development of self-cleaning SERS-active nanostructures based on ZnO nanorods and Ag nanoparticles. Journal of Physics: Conference Series, 2103, article 012128. https://doi.org/10.1088/1742-6596/2103/1/012128 (In English)
Peng, Y., Jiang, D., Zhao, M. et al. (2023) High-performance UV–visible photodetectors based on ZnO/perovskite heterostructures. Journal of Alloys and Compounds, 965, article 171372. https://doi.org/10.1016/j.jallcom.2023.171372 (In English)
Salem, M., Amor, O., Haouas, A. et al. (2025) Improved optoelectronic efficiency of CsPbBr3 perovskite thin films decorated by ZnO nanoparticles. Optical and Quantum Electronics, 57, article 446. https://doi.org/10.1007/s11082-025-08383-x (In English)
Samanta, P. K., Bandyopadhyay, A. K. (2012) Chemical growth of hexagonal zinc oxide nanorods and their optical properties. Applied Nanoscience, 2, 111–117. https://doi.org/10.1007/s13204-011-0038-8 (In English)
Saran, R., Heuer-Jungemann, A., Kanaras, A. G., Curry, R. J. (2017) Giant bandgap renormalization and exciton– phonon scattering in perovskite nanocrystals. Advanced Optical Materials, 5 (17), article 1700231. https://doi.org/10.1002/adom.201700231 (In English)
Shah, M. A. (2008) Zinc oxide nanorods prepared at low temperatures without catalyst. Modern Physics Letters B, 22 (26), 2617–2621. https://doi.org/10.1142/S0217984908017126 (In English)
Sharma, B., Frontiera, R. R., Henry, A.-I. (2012) SERS: Materials, applications, and the future. Materials Today, 15 (1–2), 16–25. https://doi.org/10.1016/S1369-7021(12)70017-2 (In English)
Sinha, G., Depero, L. E., Alessandri, I. (2011) Recyclable SERS substrates based on Au-Coated ZnO nanorods. ACS Applied Materials & Interfaces, 3 (7), 2557–2563. https://doi.org/10.1021/am200396n (In English)
Song, G., Cong, S. Zhao, Z. (2022) Defect engineering in semiconductor-based SERS. Chemical Science, 13 (5), 1210–1224. https://doi.org/10.1039/D1SC05940H (In English)
Tauc, J., Scott, T. A. (1967) Direct determination of optical absorption edge in amorphous semiconductors. Physics Today, 20 (10), 105–116. https://doi.org/10.1063/1.3033945 (In English)
Thyr, J., Osterlund, L., Edvinsson, T. (2021) Polarized and non-polarized Raman spectroscopy of ZnO crystals: Method for determination of crystal growth and crystal plane orientation for nanomaterials. Journal of Raman Spectroscopy, 52 (8), 1395–1405. https://doi.org/10.1002/jrs.6148 (In English)
Toma, F. T. Z., Rahman, M. S., Maria, K. H. (2025) A review of recent advances in ZnO nanostructured thin films by various deposition techniques. Discover Materials, 5, 60. https://doi.org/10.1007/s43939-025-00201-1 (In English)
Vo-Dinh, T., Liu, Y., Fales, A. M. et al. (2015) SERS nanosensors and nanoreporters: Golden opportunities in biomedical applications. WIREs Nanomedicine and Nanobiotechnology, 7 (1), 17–33. https://doi.org/10.1002/wnan.1283 (In English)
Wang, H., Zhang, P., Zang, Z. (2020) High performance CsPbBr3 quantum dots photodetectors by using zinc oxide nanorods arrays as an electron-transport layer. Applied Physics Letters, 116, 162103. https://doi.org/10.1063/5.0005464 (In English)
Wang, J., Zou, L., Yang, M. et al. (2023) Improvement of the stability and optical properties of CsPbBr3 QDs. Nanomaterials, 13 (16), article 2372. https://doi.org/10.3390/nano13162372 (In English)
Wang, X., Chen, Y., Zhang, W. et al. (2025) Highly sensitive and reproducible SERS substrates based on a novel 3D waffle-like PMMA–CsPbBr3–Au ternary film. Sensors and Actuators B: Chemical, 431, article 137434. https://doi.org/10.1016/j.snb.2025.137434 (In English)
Wu, L., Wu, Y, Lu, W. (2005) Preparation of ZnO Nanorods and optical characterizations. Physica E, 28 (1), 76–82. https://doi.org/10.1016/j.physe.2005.02.005 (In English)
Wu, T., Wang, A., Zheng, L. et al. (2019) Evolution of native defects in ZnO nanorods irradiated with hydrogen ion. Scientific Reports, 9, article 17393. https://doi.org/10.1038/s41598-019-53951-3 (In English)
Xia, L., Chen, M., Zhao, X. et al. (2014) Visualized method of chemical enhancement mechanism on SERS and TERS. Journal of Raman Spectroscopy, 45 (6), 524–530. https://doi.org/10.1002/jrs.4504 (In English)
Xu, Y., Aljuhani, W., Zhang, Y. et al. (2025) A practical approach to quantitative analytical surface-enhanced Raman spectroscopy. Chemical Society Reviews, 54 (1), 62–84. https://doi.org/10.1039/D4CS00861H (In English)
Yi, J., You, E. M., Hu, R. et al. (2025) Surface-enhanced Raman spectroscopy: a half-century historical perspective. Chemical Society Reviews, 54 (3), article 1453. https://doi.org/10.1039/D4CS00883A (In English)
Zhao, Y., Xu, Y., Jing, X., Ma, W. (2023) SERS-active plasmonic metal NP-CsPbX3 films for multiple veterinary drug residues detection. Food Chemistry, 412, article 135420. https://doi.org/10.1016/j.foodchem.2023.135420 (In English)
Zhou, J., Du, Z., Xie, B., Wang, B. (2025) Potential-controlled interfacial charge transfer and chemical enhancement of SERS spectra in plasmonic molecular junctions. Journal of Physical Chemistry C, 129 (7), 3646–3652. https://doi.org/10.1021/acs.jpcc.4c07711 (In English)
Загрузки
Опубликован
Выпуск
Раздел
Лицензия
Copyright (c) 2026 Валерия Анатольевна Гущина, Евгений Павлович Аверочкин, Мария Александровна Теплоногова, Егор Александрович Лебедев, Сергей Александрович Козюхин

Это произведение доступно по лицензии Creative Commons «Attribution» («Атрибуция») 4.0 Всемирная.
Авторы предоставляют материалы на условиях публичной оферты и лицензии CC BY 4.0. Эта лицензия позволяет неограниченному кругу лиц копировать и распространять материал на любом носителе и в любом формате в любых целях, делать ремиксы, видоизменять, и создавать новое, опираясь на этот материал в любых целях, включая коммерческие.
Данная лицензия сохраняет за автором права на статью, но разрешает другим свободно распространять, использовать и адаптировать работу при обязательном условии указания авторства. Пользователи должны предоставить корректную ссылку на оригинальную публикацию в нашем журнале, указать имена авторов и отметить факт внесения изменений (если таковые были).
Авторские права сохраняются за авторами. Лицензия CC BY 4.0 не передает права третьим лицам, а лишь предоставляет пользователям заранее данное разрешение на использование при соблюдении условия атрибуции. Любое использование будет происходить на условиях этой лицензии. Право на номер журнала как составное произведение принадлежит издателю.





