Relaxation methods for studying transformations in polymer systems

Authors

DOI:

https://doi.org/10.33910/2687-153X-2020-1-3-93-98

Keywords:

self-organization, nuclear magnetic relaxation, polymers, relaxation processes, microcontainers

Abstract

It is known that self-organisation of nanostructures according to the bottom-up approach is driven by the competition of several processes: surface tension, diffusion, gravity, buoyant force and, perhaps, molecular coordination phenomenon. The last one was discussed in the 70s in terms of the so-called “mobile organised molecular arrays” and proved with the help of nuclear magnetic relaxation. This study shows examples of self-organised structures obtained electrochemically by authors and provides a discussion regarding the same terms.

References

Ammam, M. (2012) Electrophoretic deposition under modulated electric fields: A review. RSC Advances, 2 (20), 7633–7646. DOI: 10.1039/C2RA01342H (In English)

Basin, V. E., Korsunskii, L. M., Shokal’skaya, O. Yu., Aleksandrov, N. V. (1972) O korrelyatsii stabil’nosti nadmolekulyarnoj struktury epoksidnykh smol s ikh elektrofizicheskimi svojstvami [Correlation of the supermolecular structure stability of epoxy resins with their electrophysical properties]. Vysokomolekulyarnye soedineniya. Seriya A — Polymer Science. Series A, 14 (9), 2085–2089. (In Russian)

Berlin, A. A., Korolev, G. V., Kefeli, T. Ya., Sivergin, Yu. M. (1983) Akrilovye oligomery i materialy na ikh osnove [Acrylic oligomers and materials based on them]. Moscow: Khimiya Publ., 232 p. (In Russian)

Berlin, A. A. (1970) Vliyanie nadmolekulyarnykh obrazovanij v zhidkikh oligomerakh na kinetiku ikh polimerizatsii i svojstva obrazuyushchikhsya vysokopolimerov [Supermolecular aggregates in liquid oligomers and their effect of kinetics of polymerization and properties of the high polymers]. Vysokomolekulyarnye soedineniya. Seriya A — Polymer Science. Series A, 12 (10), 2313–2325. (In Russian)

Berlin, A. A., Kireeva, S. M., Sivergin, Yu. M. (1974) O morfologii, relaksacionnykh i predel’nykh mehanicheskikh svojstvakh trehmernykh polimerov oligoefirakrilatov [On the morphology, relaxation and limiting mechanical properties of three-dimensional polymers of oligoester acrylates]. Dep. to VINITI AN SSSR, 1650–1674, 161. (In Russian)

Berlin, A. A., Tvorogov, N. N., Korolev, G. V. (1966) O fotopolimerizatsii dimetakrilovykh efirov glikolej [About photopolymerization of dimethacrylic esters of glycols]. Izvestiya Akademii Nauk SSSR. Khimicheskaya seriya — Bulletin of the Academy of Science of the USSR. Chemical Series, 1, 193–199. (In Russian)

Besghini, D., Mauri, M., Simonutti, R. (2019) Time domain NMR in polymer science: From the laboratory to the industry. Applied Sciences, 9 (9), article 1801. DOI: 10.3390/app9091801 (In English)

Bloembergen, N., Purcell, E. M., Pound, R. V. (1948) Relaxation effects in nuclear magnetic resonance absorption. Physical Review, 73 (7), 679–715. DOI: 10.1103/PhysRev.73.679 (In English)

Borisova, T. I., Budovskaya, L. D., Ivanova, V. N., Nikonorova, N. A., Rostovskii, Ye. N., Chichagova, Ye. R., Shevelev, V. A. (1980) Issledovanie molekulyarnogo dvizheniya v grebneobraznykh poliftoralkilakrilatakh i metakrilatakh metodami dielektricheskoj i yadernoj magnitnoj relaksatsii [The study of molecular motion in comblike polyfluoroalkylacrylates and methacrylates using dielectric and nuclear magnetic relaxation technique]. Vysokomolekulyarnye soedineniya. Seriya A — Polymer Science. Series A, 22 (12), 2672–2681. (In Russian)

Cole, K. S., Cole, R. H. (1941) Dispersion and absorption in dielectrics I. Alternating current characteristics. The Journal of Chemical Physics, 9 (4), 341–351. DOI: 10.1063/1.1750960 (In English)

Davidson, D. W., Cole, R. H. (1951) Dielectric relaxation in glycerol, propylene glycol, and n-propanol. The Journal of Chemical Physics, 19 (12), 1484–1490. DOI: 10.1063/1.1748105 (In English)

Debye, P. J. W. (1929) Polar molecules. New York: The Chemical Catalog Company, Inc., 172 p. DOI: 10.1002/ jctb.5000484320 (In English)

Erath, E. H., Spurr, R. A. (1959) Occurrence of globular formations in thermosetting resins. Journal of Polymer Science, 35 (129), 391–399. DOI: 10.1002/pol.1959.1203512907 (In English)

Faynman, R. P. (1960) There’s plenty of room at the bottom. Engineering and Science, 23 (5), 22–36. (In English)

Frenkel, J. (1946) Kinetic theory of liquids. Oxford: Oxford University Press, 485 p. (In English)

Fröhlich, H. (1958) Theory of dielectrics: Dielectric constant and dielectric loss. 2nd ed. Oxford: Clarendon Press, 192 p. (In English)

Fuoss, R. M., Kirkwood, J. G. (1941) Electrical properties of solids. VIII. Dipole moments in polyvinyl chloride-diphenyl systems. Journal of the American Chemical Society, 63 (2), 385–394. DOI: 10.1021/ja01847a013 (In English)

Gasilova, E. R., Shevelev, V. A., Ginzburg, L. I., Tarkova, E. M. (1993) Issledovanie fazovogo sostava i stepeni sshivaniya dispersnoj uprochnyayushchej fazy udaroprochnogo polistirola s pomoshch’yu protonnoj magnitnoj relaksatsii [Study of phase composition and crosslinking in dispersed strengthening phase of high impact strength polystyrene by 1H magnetic relaxation]. Vysokomolekulyarnye soedineniya. Seriya A — Polymer Science. Series A, 35 (3), 280–284. (In Russian)

Gvozdetskii, A. N., Azizov, A. G., Gorbunova, N. V., Kabanov, V. A. (1968) O roli labil’nykh zagotovok pri sopolimerizatsii akrilonitrila s metilmetakrilatom pri temperaturnykh fazovykh perekhodov steklo—kristall [About role of mobile organized molecular arrays at copolymerization of acrylonitrile with methylmethacrylate at temperatures of phase transitions glass—crystall]. Vysokomolekulyarnye soedineniya. Seriya A — Polymer Science. Series A, 10 (8), 1817–1822. (In Russian)

Havriliak, S., Negami, S. (1967) A complex plane representation of dielectric and mechanical relaxation processes in some polymers. Polymer, 8, 161–210. DOI: 10.1016/0032-3861(67)90021-3 (In English)

Iroh, J. O., Zhu, Y., Shah, K. et al. (2003) Electrochemical synthesis: A novel technique for processing multi-functional coatings. Progress in Organic Coatings, 47 (3–4), 365–375. DOI: 10.1016/j.porgcoat.2003.07.006 (In English)

Lehn, J.-M. (1988) Supramolecular chemistry — scope and perspectives. Molecules, supermolecules, and molecular devices (Nobel Lecture). Angewandte Chemie, International Edition, 27 (1), 89–112. DOI: 10.1002/anie.198800891 (In English)

Levine, K. L., Guolian, Ch., He, J. et al. (2015) Unusual Polypyrrole structures observed during electrodeposition of Polypyrrole. In: CPM poster session: NDSU-2015. August 2015. Conference Proceedings. NDSU, Fargo ND, USA. (In English)

Levine, K. L., Nikonorova N. A., Khanin S. D. (2019) Protsessy samoorganizatsii pri polimerizatsii i elektropolimerizatsii v polimernykh sistemakh [Self-organisation processes under polymerization and electropolymerizing in polymer systems]. In: XIII St. Petersburg congress “Professional education, science and innovations in XXI century”. 20–22 November, 2019. Conference Proceedings. Saint Petersburg: Saint Petersburg Mining University Publ., 128–131. (In Russian)

Nicolis, G., Prigogine, I. (1977) Part IV. Control mechanisms in chemical and biologycal systems. In: G. Nicolis, I. Prigogine. Self-organization in nonequilibrium systems: From dissipative structures to order through fluctuations. New York: Wiley InterScience, 339–426. (In English)

Nishida, M., Tanaka, T., Hayakawa, Y., Nishida, M. (2018) Solid-state nuclear magnetic resonance (NMR) and nuclear magnetic relaxation time analyses of molecular mobility and compatibility of plasticized polyhydroxyalkanoates (PHA) copolymers. Polymers, 10 (5), article 506. DOI: 10.3390/polym10050506 (In English)

Sapurina, I. Yu., Shishov, M. A. (2012) Oxidative polymerization of aniline: Molecular synthesis of polyaniline and the formation of supramolecular structures. In: A. de Souza Gomes (ed.). New polymers for special applications. Croatia: IntechOpen Publ., 251–312. DOI: 10.5772/48758 (In English)

Spurr, R. A., Erath, E. H., Myers, H., Pease, D. C. (1957) Curing process in phenolic resins electron-microscopic analysis. Industrial & Engineering Chemistry, 49 (11), 1839–1842. DOI: 10.1021/ie50575a027 (In English)

Strzelecki, I., Liebert, L. (1973) Sur la synthèse de quelques nouveaux monomères mesomorphes. Polymérization de la p-acryloyloxybenzylidene p-carboxyaniline. Bulletin de la Société Chimique de France, 2, 603–604. (In French)

Wong, T. C. (2006) Micellar systems: Nuclear magnetic resonance spectroscopy. In: N. Somasundaran (ed.). Encyclopedia of surface and colloid science. Vol. 5. 2nd ed. New York: Taylor & Francis, 3738–3756. (In English).

Published

2020-09-21

Issue

Section

Condensed Matter Physics