Dielectric properties of photoanodes for dye-sensitized solar cells
DOI:
https://doi.org/10.33910/2687-153X-2024-5-1-10-17Keywords:
dielectric properties, mesoporous layer, titanium dioxide, dye-sensitized solar cells, composite materials, organic dyesAbstract
Solar energy (SE) research is relevant today, especially as far as dye-sensitized solar cells (DSSC) are concerned, which are third-generation devices. The prospect of their future development lies in the creation of architectural and interior-integrated panels, flexible and portable devices for SE conversion. Examining the properties of their components and their mutual impact is crucial for improving the efficiency of DSSC and moving away from the standard cell design.
In this work, we investigated dielectric properties of photoanodes (PhA) for DSSC. The influence of a dye on dielectric properties of PhA is shown. By measuring dielectric properties in the samples, we obtained dielectric permittivity and dielectric loss tangent that ranged from –50 to 150 °C and from 10-1 to 106 Hz.
Our results make a significant contribution towards a better understanding of the influence that the dye has on dielectric properties of PhA and can serve to develop new efficient composite materials for new-generation photoelectronic devices.
References
Berni, A., Mennig, M., Schmidt, H. (2004) Doctor Blade. In: M. A. Aegerter, M. Mennig (eds.). Sol-Gel technologies for glass producers and users. Boston: Springer Publ., pp. 89–92. https://doi.org/10.1007/978-0-387-88953-5_10 (In English)
Bonkerud, J., Zimmermann, C., Weiser, P. M. et al. (2021) On the permittivity of titanium dioxide. Scientific Reports, 11 (1), article 12443. https://doi.org/10.1038/s41598-021-92021-5 (In English)
Huang, J., Lim, P. C., Shen, L. et al. (2005) Cubic silsesquioxane-polyimide nanocomposites with improved thermomechanical and dielectric properties. Acta Materialia, 53 (8), 2395–2404. https://doi.org/10.1016/j.actamat.2005.02.001 (In English)
Kim, J.-H., Han, S.-H. (2020) Energy generation performance of window-type dye-sensitized solar cells by color and transmittance. Sustainability, 12 (21), article 8961. https://doi.org/10.3390/su12218961 (In English)
Mohamed, J. J., Hutagalung, S. D., Ain, M. F., Ahmad, Z. A. (2011) Effect of excess TiO2 in CaCu3Ti4O12 on the microstructure and dielectric properties. Journal of Ceramic Processing Research, 12 (5), 496–499, http://dx.doi.org/10.36410/jcpr.2011.12.5.496 (In English)
O’Regan, B., Gratzel, M. (1991) A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 353, 737–740. https://doi.org/10.1038/353737a0 (In English)
Ramesan, M. T. (2015) Processing characteristics and mechanical and electrical properties of chlorinated styrenebutadiene rubber/fly ash composites. Journal of Thermoplastic Composite Materials, 28 (9), 1286–1300. https://doi.org/10.1177/0892705713505611 (In English)
Romeu, M. C., Oliveira, R. G. M., Sales, A. J. M. (2013) Impedance spectroscopy study of TiO2 addition on the ceramic matrix Na2Nb4O11. Journal of Materials Science: Materials in Electronics, 24 (12), 4993–4999. https://doi.org/10.1007/s10854-013-1514-6 (In English)
Steparuk, A. S., Irgashev, R. A., Zhilina, E. F. et al. (2022) Performance evaluation of dye-sensitized solar cells (DSSCs) based on metal-free thieno[3,2-b]indole dyes. Journal of Materials Science: Materials in Electronics, 33 (9), 6307–6317. https://doi.org/10.1007/s10854-022-07805-w (In English)
Szindler, M., Szindler, M., Drygała, A. et al. (2021) Dye-sensitized solar cell for building-integrated photovoltaic (BIPV) applications. Materials, 14 (3), article 3743. http://dx.doi.org/10.3390/ma14133743 (In English)
Wang, D. H., Goh, W. C., Ning, M., Ong, C. K. (2006) Effect of Ba doping on magnetic, ferroelectric, and magnetoelectric properties in mutiferroic BiFeO3 at room temperature. Applied Physics Letters, 88 (21), article 212907. http://dx.doi.org/10.1063/1.2208266 (In English)
Wypych, A., Bobowska, I., Tracz, M. et al. (2014) Dielectric properties and characterisation of titanium dioxide obtained by different chemistry methods. Journal of Nanomaterials, 2014, article 124814. https://doi.org/10.1155/2014/124814 (In English)
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Copyright (c) 2024 Ekaterina V. Tekshina, Petr I. Lazarenko, Alexander S. Steparuk, Darya A. Krupanova, Sergey A. Kozyukhin

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