Molecular mobility in crystallising aromatic thermoplastic polyimide R-BAPS
DOI:
https://doi.org/10.33910/2687-153X-2020-1-4-135-141Keywords:
thermoplastic aromatic polyimide, molecular mobility, dielectric spectroscopy, relaxation time, glass transition temperatureAbstract
The molecular mobility of the thermoplastic aromatic R-BAPS polyimide films based on 1,3-bis (3,3’-4,4’-dicarboxyphenoxy) benzene (dianhydride) and 4,4’-bis (4-aminophenoxy) biphenyl was studied using the dielectric method. Two relaxation regions of dipole polarisation caused by local mobility of phenylene groups in the diamine (γ process) and in the diamine and dianhydride macromolecule parts (β process) were identified in the glassy state, In the high-elastic state, two relaxation processes, α and αMWS, were also observed. The α process is due to the large-scale segmental mobility of macromolecules. The αMWS process is caused by the relaxation at the boundary between amorphous and crystalline regions, i.e., the Maxwell-Wagner-Sillars relaxation. Moreover, a structural transition due to melting was observed in the initial samples.
References
Bryant, R. G. (2002) Polyimides. In: H. F. Mark (ed.). Encyclopedia of polymer science and technology. Vol. 7. 4th ed. New York: John Wiley & Sons Publ., pp. 529–555. DOI: 10.1002/0471440264.pst272 (In English)
Cheng, S. Z. D., Chalmers, T. M., Gu, Y. et al. (1995) Relaxation processes and molecular motion in a new semicrystalline polyimide. Macromolecular Chemistry and Physics, 196 (5), 1439–1451. DOI: 10.1002/macp.1995.021960507 (In English)
Chisca, S., Musteata, V. E., Sava, I., Bruma, M. (2011) Dielectric behavior of some aromatic polyimide films. European Polymer Journal, 47 (5), 1186–1197. DOI: 10.1016/j.eurpolymj.2011.01.008 (In English)
Diaz-Calleja, R. (2000) Comment on the maximum in the loss permittivity for the Havriliak–Negami equation. Macromolecules, 33 (24), 8924–8924. DOI: 10.1021/ma991082i (In English)
Donth, E. (2001) The glass transition: Relaxation dynamics in liquids and disordered materials. Vol. 48. Berlin: Springer Science & Business Media Publ., 418 p. (In English)
Havriliak, S., Negami, S. (1967) A complex plane representation of dielectric and mechanical relaxation processes in some polymers. Polymer, 8, 161–210. DOI: 10.1016/0032-3861(67)90021-3 (In English)
Hedvig, P. (1977) Dielectric spectroscopy of polymers. Budapest: Akademiai Kiado, 312 p. (In English)
Jacobs, J. D., Arlen, M. J., Wang, D. H. et al. (2010) Dielectric characteristics of polyimide CP2. Polymer, 51 (14), 3139–3146. DOI: 10.1016/j.polymer.2010.04.072 (In English)
Kamalov, A. M., Borisova, M. E., Didenko, A. L. et al. (2020) Relaxation behavior of thermoplastic polyimide R-BAPB in the amorphous state. Polymer Science. Series A, 62 (2), 107–115. DOI: 10.1134/S0965545X20010058 (In English)
Klonos, P., Kyritsis, A., Bokobza, L. et al. (2017) Interfacial effects in PDMS/titania nanocomposites studied by thermal and dielectric techniques. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 519, 212–222. DOI: 10.1016/j.colsurfa.2016.04.020 (In English)
Lu, H., Zhang, X., Zhang, H. (2006) Influence of the relaxation of Maxwell-Wagner-Sillars polarization and dc conductivity on the dielectric behaviors of nylon 1010. Journal of Applied Physics, 100 (5), article 054104. DOI: 10.1063/1.2336494 (In English)
Neagu, E., Pissis, P., Apekis, L. (2000) Electrical conductivity effects in polyethylene terephthalate films. Journal of Applied Physics, 87 (6), 2914–2922. DOI: 10.1063/1.372277 (In English)
Nikonorova, N. A., Kononov, A. A., Dao, H. T., Castro, R. A. (2019) Molecular mobility of thermoplastic aromatic polyimides studied by dielectric spectroscopy. Journal of Non-Crystalline Solids, 511, 109–114. DOI: 10.1016/j.jnoncrysol.2018.12.032 (In English)
Riande, E., Diaz-Calleja, R. (2004) Electrical properties of polymers. New York: Marcel Dekker Publ., 630 p. (In English)
Samet, M., Levchenko, V., Boiteux, G. et al. (2015) Electrode polarization vs. Maxwell-Wagner-Sillars interfacial polarization in dielectric spectra of materials: Characteristic frequencies and scaling laws. The Journal of Chemical Physics, 142 (19), article 194703. DOI: 10.1063/1.4919877 (In English)
Smirnova, V. E., Gofman, I. V., Ivan’kova, E. M. et al. (2013) Effect of single-walled carbon nanotubes and carbon nanofibers on the structure and mechanical properties of thermoplastic polyimide matrix films. Polymer Science. Series A, 55 (4), 268–278. DOI: 10.1134/S0965545X1304007X (In English)
Sroog, C. E. (1969) Polyimides. In: H. F. Mark, N. G. Gaylord, N. M. Bikales (eds.). Encyclopedia of polymer science and technology. Vol. 11. 1st ed. New York: John Wiley & Sons Publ., pp. 247–272. (In English)
Sun, Z., Dong, L., Zhuang, Y. et al. (1992) Beta relaxation in polyimides. Polymer, 33 (22), 4728–4731. DOI: 10.1016/0032-3861(92)90684-O (In English)
Svetlichnyi, V. M., Kudryavtsev, V. V. (2003) Polyimides and the problems of designing advanced structural composite materials. Polymer Science. Series B, 45 (5-6), 140–185. (In English)
Tsonos, C., Apekis, L., Viras, K. et al. (2001) Electrical and dielectric behavior in blends of polyurethane-based ionomers. Solid State Ionics, 143 (2), 229–249. DOI: 10.1016/S0167-2738(01)00858-X (In English)
Yudin, V. E., Svetlichnyi, V. M., Gubanova, G. N. et al. (2002) Semicrystalline polyimide matrices for composites: Crystallization and properties. Journal of Applied Polymer Science, 83 (13), 2873–2882. DOI: 10.1002/app.10277 (In English)
Vallerien, S. U., Kremer, F., Boeffel, C. (1989) Broadband dielectric spectroscopy on side group liquid crystal polymers. Liquid Crystals, 4 (1), 79–86. DOI: 10.1080/02678298908028960 (In English)
Vogel, H. (1921) The law of the relation between the viscosity of liquids and the temperature. Physikalische Zeitschrift, 22, 645–646. (In English)
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