Dielectric spectroscopy of VO2 nanocrystalline films
DOI:
https://doi.org/10.33910/2687-153X-2022-3-1-43-50Keywords:
dielectric spectroscopy, vanadium dioxide films, VO2, semiconductor-metal phase transition, correlation effectsAbstract
The article describes the first reported case of applying dielectric spectroscopy to study nontrivial details of size dependences of phase transformation parameters in nanocrystallites of VO2 films. The method allows to identify the electrophysical parameters of nanocrystalline sets of different sizes and random location on the VO2 substrate. The article investigates the martensitic nature of the Mott-Peierls semiconductor-metal phase transition in crystalline VO2 films.
References
Castro, R. A., Ilinskij, A. V., Pashkevich, M. E. et al. (2021) Dielektricheskaya spektroskopiya soedinenij sil’nokorrelirovannykh elementov [Dielectric spectroscopy of compounds of strongly correlated elements]. Saint Petersburg: Fora-print Publ., 54 p. (In Russian)
Gatti, M., Bruneval, F., Olevano, V., Reining, L. (2007) Understanding correlations in vanadium dioxide from first principles. Physical Review Letters, 99 (26), article 266402. https://www.doi.org/10.1103/PhysRevLett.99.266402 (In English)
Il’inskiy, A. V., Pashkevich, M. E., Shadrin, E. B. (2017) Stage-by-stage modeling of the mechanism of semiconductor– metal phase transition in vanadium dioxide. St. Petersburg Polytechnical University Journal: Physics and Mathematics, 3 (3), 181–186. https://doi.org/10.1016/j.spjpm.2017.09.002 (In English)
Ilinskiy, A. V., Kastro, R. A., Pashkevich, M. E., Shadrin, E. B. (2020) Dielectric spectroscopy and mechanism of the semiconductor–metal phase transition in doped VO2:Ge and VO2:Mg Films. Semiconductors, 54 (4), 403–411. https://doi.org/10.1134/S1063782620040077 (In English)
Ilinskiy, A. V., Kvashenkina, O. E., Shadrin, E. B. (2012) Nature of the electronic component of the thermal phase transition in VO2 films. Semiconductors, 46 (9), 1171–1185. https://doi.org/10.1134/S1063782612090096 (In English)
Mott, N. F. (1997) Metal-insulator transitions. London: Taylor and Francis Publ., p. 286. (In English)
Prokhorov, A. M. (ed.). (1994) Fizicheskaya entsiklopediya. T. 4: Pojntinga — Robertsona strimery [Physical encyclopedia. Vol. 4: Pointing—Robertson streamers]. Moscow: Bol’shaya Rossijskaya entsiklopediya Publ., 704 p. (In Russian)
Shadrin, E. B., Il’inskii, A. V. (2000) On the nature of metal–semiconductor phase transition in vanadium dioxide. Physics of the Solid State, 42 (6), 1126–1133. https://doi.org/10.1134/1.1131328 (In English)
Downloads
Published
Issue
Section
License
Copyright (c) 2022 Rene Alejandro Castro Arata, Aleksandr V. Ilinskiy, Vladimir A. Klimov, Marina E. Pashkevish, Evgeniy B. Shadrin
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
The work is provided under the terms of the Public Offer and of Creative Commons public license Attribution-NonCommercial 4.0 International (CC BY-NC 4.0). This license allows an unlimited number of persons to reproduce and share the Licensed Material in all media and formats. Any use of the Licensed Material shall contain an identification of its Creator(s) and must be for non-commercial purposes only.